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Correlation among Morphology, Crystallinity, and Charge Mobility in OFETs Made of Quaterthiophene Alkyl Derivatives on a Transparent Substrate Platform

  Articoli su Riviste JCR/ISI  (anno 2011)

Autori:  Generali G., Dinelli F., Capelli R., Toffanin S., di Maria F., Gazzano M., Barbarella G., Muccini, M

Affiliazione Autori:  Consiglio Nazionale Delle Ricerche (CNR), Istituto per Lo Studio Dei Materiali Nanostrutturati (ISMN), via P. Gobetti 101, I-40129 Bologna, Italy; Consiglio Nazionale Delle Ricerche (CNR), INO UOS

Riassunto:  In this Article, we present a comprehensive study of organic field-effect transistors (OFETs) made of thin films of methyl, n-butyl, and n-hexyl end-substituted quaterthiophenes on a transparent substrate platform. This particular platform has been already used for organic light-emitting diodes (OLEDs) but rarely employed for OFETs. In perspective, this is a very promising route for the development of field-effect photonic applications such as organic light-emitting transistors (OLETs). A systematic characterization of the organic films has been made by means of atomic force microscopy (AFM) and X-ray diffraction (XRD) to correlate morphology, crystallinity and charge mobility to the alkyl chain length. In particular, a charge mobility value of 0.09 cm(2)/(V s) has been obtained in transparent OFETs with a large area channel for DH4T grown at room temperature. This mobility exceeds the one obtained on silicon-oxide substrates and is likely due to a more favorable interaction of the DH4T molecules with the PMMA layer employed as gate dielectric.

Volume n.:  115 (46)      Pagine da: 23164  a: 23169
Ulteriori informazioni:  Financial support from Italian MISE through project Industria 2015 (ALADIN), Consorzio MIST E-R through project FESR-Tecnopolo AMBIMAT, and EU through projects FP7-ICT-248052 (PHOTO-FET) and FP7-ICT- 247928 (LAMP) is acknowledged.
DOI: 10.1021/jp2090704

*Impact Factor della Rivista: (2011) 4.805   *Citazioni: 18
data tratti da "WEB OF SCIENCE" (marchio registrato di Thomson Reuters) ed aggiornati a:  19/05/2019

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