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Suitability of ultra-refractory diboride ceramics as absorbers for solar energy applications

  Articoli su Riviste JCR/ISI  (anno 2013)

Autori:  Sciti D., Silvestroni L., Mercatelli L., Sans J.-L., Sani E

Affiliazione Autori:  CNR - ISTEC, Institute of Science andT echnology for Ceramics, Via Granarolo 64, I-48018 Faenza, Italy; CNR - INO National Institute of Optics, Largo E. Fermi, 6, I-50125 Firenze,Italy; PROMES - CNRS Processes, Materials and Solar Energy Laboratory, 7 rue du Four Solaire ,66120 Font Romeu, France

Riassunto:  Ultra-refractory diborides are currently studied mainly as thermal protection materials for aerospace and military applications. However, their favorable properties (very high melting points and good thermo-mechanical properties at high temperatures) can be advantageously exploited to increase the operating temperature of thermodynamic solar plants in concentrating solar power systems. This paper reports on the spectral reflectance characterization of hafnium and zirconium diborides containing MoSi2 as secondary phase to evaluate their potential as novel solar absorbers. To assess the spectral selectivity properties, room-temperature hemispherical reflectance spectra were measured from the UV wavelength region to the mid-infrared, considering different levels of porosity for each system. Moreover, for zirconium diboride and hafnium diboride composites containing 10 vol% of MoSi2 sintering aid, the thermal emittance was measured in the 1100-1400 K temperature range. Room temperature spectral characteristics and high temperature emittance were compared to that of a monolithic silicon carbide. (C) 2012 Elsevier B.V. All rights reserved.

Rivista/Giornale:  SOLAR ENERGY MATERIALS AND SOLAR CELLS
Volume n.:  109      Pagine da: 8  a: 16
Ulteriori informazioni:  Financial support by the Access to Research Infrastructures activity in the 7th Framework Program of the EU (SFERA Grant Agreement no. 228296) is gratefully acknowledged, as well as the PROMES Director and PROMES Researchers for the use of facilities. Authors thank Dr. Franco Francini for useful discussions about optical properties of UHTCs, C. Melandri for roughness measurements, R. Renis for materials preparation, Mauro Pucci and Massimo D\'Uva for technical assistance.
DOI: 10.1016/j.solmat.2012.10.004

*Impact Factor della Rivista: (2013) 5.030   *Citazioni: 37
data tratti da "WEB OF SCIENCE" (marchio registrato di Thomson Reuters) ed aggiornati a:  19/05/2019

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