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Transition metal based catalysts in the aerobic oxidation of alcohols

  Articoli su Riviste JCR/ISI  (anno 2012)

Autori:  Parmeggiani C., Cardona F

Affiliazione Autori:  Ugo Schiff Univ Florence, Dept Chem, Sesto Fiorentino, FI, Italy; Univ Florence, CNR INO, Sesto Fiorentino, FI, Italy; Univ Florence, European Lab Nonlinear Spect LENS, Sesto Fiorentino, FI, Italy

Riassunto:  The oxidation of alcohols to the corresponding carbonyl compounds is a pivotal reaction in organic synthesis. However, traditional oxidants are often toxic and release considerable amounts of by-products. As an alternative, oxygen (or even better air) is among the cheaper and less polluting stoichiometric oxidants, since it produces no waste or water as the sole by-product. The implementation of a transition metal-based catalyst in combination with oxygen represents an emerging alternative to the traditional procedures. This review aims to give an overview on the most important advances made by the scientific community in the last 15 years in the field of aerobic oxidations of alcohols catalyzed by transition metals in the form of homogeneous catalysts, heterogeneous catalysts and, more recently, nanoparticles.

Rivista/Giornale:  GREEN CHEMISTRY
Volume n.:  14 (3)      Pagine da:  547  a:  564
Ulteriori informazioni:  DOI: 10.1039/C2GC16344F
DOI: 10.1039/c2gc16344f

*Impact Factor della Rivista: (2012) 6.828   *Citazioni: 378
data tratti da "WEB OF SCIENCE" (marchio registrato di Thomson Reuters) ed aggiornati a:  12/05/2019

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